The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy / t-C4H9O2,(CH3)3CO2 / Wallington(1992)_298K_210-280nm(rec)

DATAFILE: t-C4H9O2,(CH3)3CO2_Wallington(1992)_298K_210-280nm(rec).txt
NAME: 1,1,1-dimethylethylperoxy radical, tert-butylperoxy radical
FORMULA: t-C4H9O2,(CH3)3CO2
AUTHOR(YEAR): Wallington(1992)
T: 298K
λ: 210-280nm(rec)
BIBLIOGRAPHY: T.J. Wallington, P. Dagaut, and M.J. Kurylo, "Ultraviolet absorption cross sections and reaction kinetics and mechanisms for peroxy radicals in the gas phase", Chem. Rev. 92, 667-710 (1992); DOI: 10.1021/cr00012a008
COMMENTS: Recommendation based on the results of

P.D. Lightfoot, P. Roussel, B. Veyret, and R. Lesclaux, "Flash photolysis study of the spectra and self-reactions of neopentylperoxy and t-butylperoxy radicals," J. Chem.Soc. Faraday Trans. 86, 2927-2936 (1990),

C. Anastasi, I.W.M. Smith, and D.A. Parkes, "Flash photolysis study of the spectra of CH3O2 and C(CH3)3O2 radicals and the kinetics of their mutual reactions and with NO," J. Chem. Soc. Faraday Trans. I 74, 1693-1701 (1978), and

L.J. Kirsch and A. Parkes, presented at the Proceedings of the 5th Int. Symposium on Gas Kinetics, Manchester, UK, 1977, Royal Society of Chemistry, London 1977, p. 37

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